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The E-Sylum: Volume 22, Number 45, November 10, 2019, Article 17

VOCABULARY TERMS: GOLDPLATE, GOLDPLATING, PART 1

Dick Johnson submitted this entry from his Encyclopedia of Coin and Medal Terminology. Thanks. It's an important but lengthy one - I'm splitting it into two parts; here's the first. -Editor

Goldplate, Goldplating. Application of gold to any surface by electrodeposition. Because gold is an element that conducts electricity it can easily be electroplated. Developed at the same time as silverplating (which was invented in Germany in 1837 and patented in England in 1840) goldplating proved useful for coating small manufactured objects. Gold can be deposited in a very thin amount, even with a few microns the object takes on the color of gold.

All but a few metallic surfaces can be goldplated. An object can be manufactured in any metal (most often an alloy) then goldplated to give it a gold color. This is done, obviously, to reduce cost, and yet to provide an object that has most of the qualities – except weight and fineness! – of solid gold.

While any metal can be goldplated, the most practical is gilding metal, a copper-zinc bronze alloy which has excellent properties of being manufactured. There are several metals, notwithstanding, which cannot be goldplated directly, iron is one of these. However even these can be plated with an intermediate metal, like nickel, then this can be goldplated.

Goldplated objects are also called gilt or gilded (see gilding). Goldplated silver is called vermeil, it has the color of gold but the sheen of silver. While similar in color, rolled gold is a clad metal where thin strips of gold are clad to a thicker base metal before blanks are cut and the piece is struck; it is not an electrochemical process. Gold leaf is an entirely different process from goldplating – it is a physical application of thin leaves of gold, not an electrochemical one.

Color of gold in goldplating. Yellow gold is free of impurities, but tiny amounts of other elements in natural gold will color (change the hue) slightly. White gold has silver or platinum impurities, pink or red gold has copper impurities, green gold has iron impurities, and the very rare black gold has bismuth impurities.

Each of these, except black gold, can be obtained by goldplating, either in the tank at the time of goldplating, or afterwards. Yellow gold is obtained by "pure" goldplating without any other metal ions in the plating solution. While white gold could be plated with silver or platinum, the same results can be obtained with tin (as sodium stannate) or nickel in the plating solution. Copper is introduced into the solution for a pink or red gold. For a green gold effect, the object is plated with silver (potassium silver cyanide) and lead acetate. See Gold Color Chart, gold.

History of goldplating. Prior to 1840 objects were covered with gold by laying on gold leaf, or by firegilding, a process employing mercury. The mercury fumes driven off were harmful to workers so the process was prohibited in advanced countries, replaced for the most part by goldplating.

But firegilding continued even in America up to 1880s. Early electrolysis was run off primitive batteries; with the introduction of commercial electricity in the 1880s it became economical to do extensive gold and silverplating. This finally eliminated firegilding entirely.

The earliest goldplating was done in quite small containers. The field has progressed, as one writer indicated, from the pint jar to the 50-gallon tank. However with the high cost of gold anodes, goldplating is done in small batches in small tanks. (Further details, identifying the people credited for developing electroplating, is given in the entry under electrolysis.)

Technique of goldplating. An anode of pure gold is required; the work – the object to be goldplated – becomes the cathode. Both are placed in an electrolytic solution, a cyanide bath containing some gold ions already in solution. Both are wired to complete an electrical circuit and the current supplied through a rectifier. Ions of gold are electrically charged and leach from the positive anode.

The ions in the electrolyte solution are attracted to the cathode that is negatively charged and instantly deposited on the cathode (object). Time is a critical factor. The longer the object remains in the solution and the current is on – the greater the thickness of gold builds up on the object. See electroplate, electroplating.

Goldplating thickness. Most goldplating is very thin with a brief time in the tank. A thin plating – called flash plate, or particularly for gold, a gold wash – is suitable only to give the object a gold color. This can be as thin as .000001 of an inch with a cost averaging 60 cents per square foot when gold was $150 an ounce (or 250th the cost of an ounce of gold). Such a plated piece cannot be finished in any manner other than lacquering. At this stage the gold can be rubbed off with repeated rubbing of human skin (collecting in the skin's pores or finger ridges).

Longer time – and thicker plating – give a deeper coating of gold. This will be reflected in both color and texture of the piece, entirely resembling gold on all surface exposed in the electrolytic tank. heavy goldplate is a result of this thicker coating, it has been identified on some items made before 1900 as XX or even XXX (triple X or triple plate) gold. This thicker plating must be reflected in the higher cost, fifty to sixty dollars per square foot (one-third the cost of an ounce of gold) because of the greater amount of gold being deposited.

Additional plating or hardness can be made by removing the item from the goldplating tank and placing it in the silver tank for only a short time. Adding one part silver say, to 50 parts gold, increases the hardness but still retains the gold color. See hard goldplate.

Advantages of goldplating. Several reasons exist for goldplating medals: (1) gold medals are a class of award medals, (2) gilding is a popular form of finish, (3) gold is a desirable color for medals as a gift, jewelry or award item, (4) gold does not discolor skin when worn on the body, (5) gold covers up surface discolorations and shallow imperfections of manufacture, (6) it is a time-honored metallic color, and, perhaps most important, (7) gold finish does not tarnish.

Medals can be easily goldplated because of their size and shape, thus goldplating is widely done in the medallic field. Thousands of medals can be goldplated from a single ounce of gold, the unit cost can be comparatively low even in times when the cost of gold is high. Medals, obviously, are goldplated rather than struck in solid gold to reduce cost.

The second part of this entry will appear in next week's issue. -Editor

Book lovers should be word lovers as well.

Looking for the meaning of a numismatic word, or the description of a term?  Try the Newman Numismatic Portal's Numismatic Dictionary at: https://nnp.wustl.edu/library/dictionary

Or if you would like a printed copy of the complete Encyclopedia, it is available. There are 1,854 terms, on 678 pages, in The Encyclopedia of Coin and Medal Technology. Even running two a week would require more than 19 years to publish them all. If you would like an advance draft of this vital reference work it may be obtained from the author for your check of $50 sent postpaid. Dick Johnson, 139 Thompson Drive, Torrington, CT 06790.

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Wayne Homren, Editor

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